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21.
本文采用去离子水和无水乙醇两种工质,利用微通道流动沸腾同步测量实验系统,研究了液膜厚度的瞬态变化规律,实验发现流动沸腾形成的初始液膜厚度在毛细数Ca很宽的范围内都遵循Taylor流动原理;液膜形成后,在蒸发和蒸汽流动携带的耦合作用下,厚度迅速减薄直至蒸干;由于水的汽液黏度比小,速度梯度小,剪切作用带来的液膜厚度减少量小,且水的汽化潜热大,吸收相同热量时蒸发量小,导致水的液膜厚度变化斜率较小,通过理论分析提出了沸腾液膜厚度变化的计算模型,计算结果与实验结果的误差小于20%。 相似文献
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AbstractThe present work is concerned with the 2D deformation in a nonhomogeneous, isotropic, micropolar, magneto-thermoelastic medium in the context of Lord-Shulman theory as a result of an inclined load. The inclined load is supposed to be a linear combination of normal load and tangential load. Material properties are assumed to be graded in x-direction. Normal mode technique is proposed to obtain the analytical expressions for the temperature field, displacement components, and stresses. These are also calculated numerically and depicted graphically to observe the variations of the considered physical variables.Communicated by Seonho Cho. 相似文献
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《Stochastic Processes and their Applications》2020,130(12):7547-7574
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We consider the random‐cluster model (RCM) on with parameters p∈(0,1) and q ≥ 1. This is a generalization of the standard bond percolation (with edges open independently with probability p) which is biased by a factor q raised to the number of connected components. We study the well‐known Fortuin‐Kasteleyn (FK)‐dynamics on this model where the update at an edge depends on the global geometry of the system unlike the Glauber heat‐bath dynamics for spin systems, and prove that for all small enough p (depending on the dimension) and any q>1, the FK‐dynamics exhibits the cutoff phenomenon at with a window size , where λ∞ is the large n limit of the spectral gap of the process. Our proof extends the information percolation framework of Lubetzky and Sly to the RCM and also relies on the arguments of Blanca and Sinclair who proved a sharp mixing time bound for the planar version. A key aspect of our proof is the analysis of the effect of a sequence of dependent (across time) Bernoulli percolations extracted from the graphical construction of the dynamics, on how information propagates. 相似文献
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Nagaraju Kerru Lalitha Gummidi Surya Narayana Maddila Sandeep V.H.S. Bhaskaruni Sreekantha B. Jonnalagadda 《应用有机金属化学》2020,34(5):e5590
The bismuth loaded on fluorapatite (Bi2O3/FAp) proved to be an excellent catalyst for the synthesis of novel dihydro-[1,2,4]triazolo[1,5-a]pyrimidine derivatives via a three-component reaction involving the mixture of 1H-1,2,4-triazol-5-amine, ethyl cyanoacetate or ethyl acetoacetate, and different benzaldehydes in ethanol at room temperature. The catalyst material was characterized by X-ray diffraction, Brunauer–Emmett–Teller surface area analysis, Fourier-transform infrared, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and transmission electron microscopy techniques. The efficacy of Bi2O3/FAp as a heterogeneous catalyst was evaluated with the loading of different wt% of bismuth on FAp. The 2.5% bismuth on FAp performed extremely well as a catalyst with a high yield of products (92%–96%) in a short reaction time (25–35 min). The catalyst was recovered by simple filtration. It showed undiminished activity up to five runs. Simple work-up, room temperature reaction, short reaction time, high yields, no column chromatography, and good reusability of catalyst are the merits of the proposed protocol. In addition, this process offers 100% carbon efficiency and 98% atom economy with noteworthy fiscal and environmental benefits. 相似文献
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Renny Mathew Karolina A. Uchman Lydia Gkoura Chris J. Pickard Maria Baias 《Magnetic resonance in chemistry : MRC》2020,58(11):1018-1025
A combined experimental and computational approach was used to distinguish between different polymorphs of the pharmaceutical drug aspirin. This method involves the use of ab initio random structure searching (AIRSS), a density functional theory (DFT)-based crystal structure prediction method for the high-accuracy prediction of polymorphic structures, with DFT calculations of nuclear magnetic resonance (NMR) parameters and solid-state NMR experiments at natural abundance. AIRSS was used to predict the crystal structures of form-I and form-II of aspirin. The root-mean-square deviation between experimental and calculated 1H chemical shifts was used to identify form-I as the polymorph present in the experimental sample, the selection being successful despite the large similarities between the molecular environments in the crystals of the two polymorphs. 相似文献
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MAX相是一类具有层状结构的三元碳化物或(和)氮化物,M是过渡金属元素,A主要是ⅢA~ⅤA族元素,X是C或N元素。这类化合物兼具陶瓷材料和金属材料的特点,具有优异的导电、导热、耐腐蚀以及抗氧化等性能,在诸多领域具有潜在应用价值。近年来,新元素、新结构和固溶体MAX相的不断出现,进一步扩展了MAX相家族。固溶体MAX相是将合适的元素固溶到已知MAX相中而得到的新MAX相。本文分四类总结了127种MAX相固溶体,对其结构改变和性能调控进行了概括,并指出目前研究存在的理论问题和亟须解决的关键技术,最后对MAX相固溶体的发展进行了预测和展望。 相似文献
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Mossel and Ross raised the question of when a random coloring of a graph can be reconstructed from local information, namely, the colorings (with multiplicity) of balls of given radius. In this article, we are concerned with random 2-colorings of the vertices of the -dimensional hypercube, or equivalently random Boolean functions. In the worst case, balls of diameter are required to reconstruct. However, the situation for random colorings is dramatically different: we show that almost every 2-coloring can be reconstructed from the multiset of colorings of balls of radius 2. Furthermore, we show that for , almost every -coloring can be reconstructed from the multiset of colorings of 1-balls. 相似文献